Non-enzymatic acylative kinetic resolution of primary allylic amines.
نویسندگان
چکیده
A non-enzymatic acetyl transfer-based kinetic resolution of primary allylic amines is reported. The process involves the use of (1S,2S)- in conjunction with a supported ammonium salt and affords the corresponding enantio-enriched N-acetylated allylic amines with unprecedented levels of selectivity (s-factors up to 34).
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 81 شماره
صفحات -
تاریخ انتشار 2013